مشخصات پژوهش

عنوان	Selective indirect electrochemical oxidation of sulfides and thiols using DDQ as an efficient and cost-effective electrocatalys
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	DDQ, Electrocatalyst, Cyclic voltammetry, Oxidation, Sulfides, Thiols, Sulfoxide, Disulfide
چکیده	The efficient oxidation of sulfides to sulfoxides and the oxidative coupling of thiols to disulfides was per- formed electrochemically in the presence of DDQ as an electrocatalyst. The electrochemical reactions were conducted in a mixture of water and acetonitrile as solvent under constant potential (0.6 V vs Ag/AgCl) for regeneration of DDQ at room temperature and the products were selectively produced in good to high yields. The electrocatalytic properties of the applied electrocatalyst for the oxidation of sub- strates and the proposed electrocatalytic mechanism were investigated by the cyclic voltammetry (CV) technique. The proposed electrochemical regeneration of DDQ can be developed for the synthesis of dif- ferent organic compounds in a single operation under mild conditions
پژوهشگران	حمید محمودی (نفر اول)، عبدالله سلیمی (نفر دوم)، امین رستمی (نفر سوم)