مشخصات پژوهش

عنوان	Structure−Property Relationships of Nanosheeted 3D Hierarchical Roughness MgAl−Layered Double Hydroxide Branched to an Electrospun Porous Nanomembrane: A Superior Oil-Removing Nanofabric
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	nanosheeted LDH, porous nanomembranes, oil-removing, superhydrophobic, superoleophilic, recyclability
چکیده	A straightforward approach was successfully developed to fabricate a well-designed three-dimensional rough sheetlike MgAl−layered double hydroxide (LDH) array to stand vertically on poly(acrylonitrile) porous nanofibrous membranes based on an electrospun-nanofiber-templated in situ hydrothermal strategy, and then the surface was modified with cyclohexanecarboxylic acid. The as-spun highly dense ordered sheetlike LDH porous nanofabric exhibited a superior durability in superhydrophobicity and superoleophilicity, which has achieved high oil-removing capability including both oil harvesting and oil separation to harvest/separate a wide range of organic solvents and oils from an oil−water mixture and, especially, exhibited a very good recycling and reusing performance. Interestingly, a steady water repellency was obtained against both drinkable hot (about 95 °C) and cool water. Outstanding oil harvesting, oil separation, and highly durable water repellant can be attributed to an effective synergistic effect between the high-density roughness of LDH nanosheets modified with acid and the very high porosity in the electrospun nanofibers, as well as the interspace between LDH nanosheets that acted as both a textile for selective oil separation and a container for penetrated oil storage, leading to special wettability, making the as-spun nanofabric a promising textile for large-scale removal and recollection of hydrophobic spillage on the water surface.
پژوهشگران	پگاه شاکری (نفر سوم)، سیدمجتبی امینی نسب (نفر دوم)، زاهد شمی (نفر اول)