عنوان
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Synthesis of Iridium Oxide Nanotubes by Electrodeposition into Polycarbonate Template: Fabrication of Chromium(III) and Arsenic(III) Electrochemical Sensor
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Iridium oxide, Nanotubes, Glassy carbon, Electrodeposition, Cr(III), As(III), Sensors
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چکیده
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For the first time iridium oxide (IrO2) nanotubes are synthesized by electrodeposition in a polycarbonate (PC) template. Potential cycling (90 cycles) between 0.0 and 0.9 V is used for the preparation of IrOx nanotubes onto the PC template with a pore diameter of 100 nm. Field-emission scanning electron microscopy (FESEM) images show, that IrO2 nanotubes with uniform diameters of 110_10 nm and an estimated length of 1–3 mm are formed. The electrochemical properties and the electrocatalytic activity of a glassy carbon-IrOx nanotube modified electrode toward Cr3+ and As3+ oxidation are investigated. Finally, the modified electrode is used for micromolar detection of the proposed analytes using differential pulse voltammetry.
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پژوهشگران
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محمد الماسی کاشی (نفر پنجم)، عبدالله رمضانی (نفر چهارم)، رحمان حلاج (نفر سوم)، عبدالله سلیمی (نفر دوم)، عرفان مفاخری (نفر اول)
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