عنوان
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p-Toluenesulfonyl Chloride (p-TsCl)-Catalyzed Trimethylsilylation of Hydroxyl Groups Using Hexamethyldisilazane and Their Regeneration Under Mild Conditions: The First Example for Catalytic Application of p-Toluenesulfonyl Chloride
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Hexamethyldisilazane; hydroxyl group; p-toluenesulfonyl chloride; trimethylsilylation
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چکیده
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The first catalytic application of p-toluenesulfonyl chloride (p-TsCl) for the efficient and selective trimethylsilylation of various types of hydroxyl groups with hexamethyldisilazane (HMDS) in dichloromethane and desilylation of these compounds in water is reported. The reactions were carried out at room temperature and were found to proceed in good to excellent yields.
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پژوهشگران
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فاطمه منتشلو (نفر سوم)، امین رستمی (نفر دوم)، اردشیر خزائی (نفر اول)
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