مشخصات پژوهش

صفحه نخست /Novel and Highly Effective ...
عنوان Novel and Highly Effective Method for the Trimethylsilylation of Alcohols and Phenols with Hexamethyldisilazane (HMDS), Catalyzed by I2 Generated in situ Using Fe(NO3)3 • 9 H2O/NaI under Heterogeneous and Neutral Conditions
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Trimethylsilylation -Alcohols-Phenols-Hexamethyldisilazane-I2 Generated in situ
چکیده Structurally diverse alcohols and phenols were trimethylsilylated in a clean and efficient reaction with hexamethyldisilazane (HMDS) based on the use of I2 generated in situ from Fe(NO3)3 • 9 H2O/NaI. The reaction occurs very rapid in good-to-high yield in CH2Cl2 at room temperature, and the use of toxic and corrosive molecular I2 is avoided.
پژوهشگران امین رستمی (نفر سوم)، اردشیر خزائی (نفر اول)، صادق رحمتی (نفر دوم)