عنوان
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A Mild Method for the Protection of Aldehydes as Dithioacetals and Dithiolanes Catalyzed by I2 Generated in situ Using Fe(NO3)3.9H2O/NaI Under Heterogeneous Conditions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Aldehydes-Ethane-1,2-dithiol-Thiophenol-Fe(NO3)3.9H2O/NaI-in situ I2- Thioacetalization-Dithiolanation.
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چکیده
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Structurally diverse aromatic aldehydes were thioacetalated in a clean and efficient reaction with ethane 1,2-dithiol and thiophenol based on the use of I2 generated in situ from Fe(NO3)3.9H2O/NaI. The reaction occurs in good to high yield in dichloromethane at room temperature and the use of toxic and corrosive molecular iodine is avoided.
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پژوهشگران
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اردشیر خزائی (نفر چهارم)، زهرا توده روستا (نفر سوم)، حیدرعلی علوی نیک (نفر دوم)، امین رستمی (نفر اول)
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