عنوان
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Solvent-Free and Selective Oxidation of Hydroxy Groups to their Corresponding Carbonyl Functions with Ferric Nitrate Activated by Heteropoly Acids
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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alcohols, carbonyl compounds, ferric nitrate, heteropoly acids, oxidations
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چکیده
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Keggin-type heteropoly acids revealed high catalytic activity for swift and selective oxidation of various hydroxy functionalities to the corresponding carbonyl groups using ferric nitrate as an oxidant under mild and solvent-free conditions. We have found that the catalytic activities of the heteropoly acids were much higher than mineral or solid acids such as sulfuric acid, p-toluenesulfonic acid, triflic acid, acidic Amberlyst-15, Montmorillonite-K10 clay, and HY-zeolite.
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پژوهشگران
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کمال امانی (نفر سوم)، ن. ایرانپور (نفر دوم)، ه. فیروزآبادی (نفر اول)
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