مشخصات پژوهش

عنوان	Oxovanadium(IV) Schiff base complexes derived from2,20-dimethylpropandiamine: A homogeneous catalystfor cyclooctene and styrene oxidation
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Schiff base; Oxovanadium; Catalyst; Olefins; tert-butylhydroperoxide
چکیده	Tetradentate Schiff base ligands, derived from aromatic aldehydes and aliphatic diamine (2,2′-dimethylpropandiamine), and their vanadyl complexes has been prepared and characterized. Catalytic potential of these complexes was tested for the oxidation of cyclooctene and styrene using tert-butylhydroperoxide (TBHP) as oxidant. The effects of molar ratio of oxidant to substrate, temperature and solvent have been studied. Excellent selectivity of epoxidation for cyclooctene and good selectivity for styrene was obtained. The mechanism of oxidation has also been discussed.
پژوهشگران	سعید رعیتی (نفر اول)، مرجان کولیایی (نفر دوم)، فاطمه آشوری (نفر سوم)، سجاد محبی (نفر چهارم)، آندرزج وتژزاک (نفر پنجم)، آنا کوزاکیوز (نفر ششم به بعد)