عنوان
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1,3-Dichloro-5,5-dimethylhydantoin (DCH) and Trichloromelamine (TCM) as Efficient Catalysts for the Chemoselective Trimethylsilylation of Hydroxyl Group with 1,1,1,3,3,3-Hexamethyldisilazane (HMDS) under Mild Conditions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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1,3-Dichloro-5,5-dimethylhydantoin (DCH); Trichloromelamine (TCM); Trimethylsilylation; Hexamethyldisilazane (HMDS).
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چکیده
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A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence of 1,3-dichloro-5,5-dimethylhydantoin (DCH) and/or trichloromelamine (TCM) as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected in CH2Cl2/CH3CN under mild conditions.
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پژوهشگران
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رویا ایازی نصرآبادی (نفر پنجم)، محمدعلی زلفی گل (نفر سوم)، کمال امانی (نفر دوم)، آرش قربانی چقامارانی (نفر اول)، مریم حجامی (نفر چهارم)
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