عنوان
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Smartphone-based microfluidic chip modified using pyrrolidine-1- dithiocarboxylic acid for simultaneous colorimetric determination of Cr3+ and Al3+ ions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Colorimetric Chromium and Aluminum determination Silver nanoparticles Microfluidic chip devices Water samples analysis
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چکیده
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A portable m-chip-based colorimetric device was developed for the determination of Cr3+ and Al3+ ions. The silver nanoparticles were modified with pyrrolidine-1-dithiocarboxylic acid ammonium salt as a novel ligand for the first time. The color of modified AgNPs in the test zone immediately changes after the addition of Cr3+ and Al3+ ions. The resulting color changes were detected by the naked eye or were taken by a smartphone camera. The obtained images were analyzed by RGB software to assay the Cr3+ and Al3+ ions concentration. Under optimized experimental conditions, the linear ranges are 0.1–220 and 0.01–250 mM for Cr3+ and Al3+ ions, respectively. The probe has a limit of detections of 10.66 and 3.55 nM for Cr3+ and Al3+ in an aqueous solution. In the case of m-chip, the concentration ranges are 0.1–200 lM and 0.01–220 lM for Cr3+ and Al3+ ions, with detection limits of 9.18 and 2.30 nM, respectively. The m-chip showed great potential as a fast detection tool for the monitoring of Cr3+ and Al3+ ions in real samples such as river water samples
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پژوهشگران
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غلامرضا خیاطیان (نفر دوم)، هدا طاهری (نفر اول)
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