مشخصات پژوهش

صفحه نخست /Synthesis of ...
عنوان Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها SBA-15 · C–S coupling · S8 · Thiourea · Aryl halide · Diaryl sulfide
چکیده In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO3)2 as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N2 sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.
پژوهشگران زکیه یوسفوند (نفر اول)، مریم حجامی (نفر دوم)، فرشید قربانی چقامارانی (نفر سوم)، راضیه غفوری نژاد (نفر چهارم)