عنوان
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Co(II)-catalyzed regioselective clean and smooth synthesis of 2-(aryl/alkylthio) phenols via sp2 C-H bond activation
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Cobalt catalyst, Homogeneous catalyst, C-H bond activation, 2-(aryl/alkyl-thio) phenol
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چکیده
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The first example of a smooth, practical and useful strategy for the preparation of ortho-aryl/alkyl sulfenyl phenols by using the reaction of aryl/alkyl thiols with phenols in the presence cobalt as catalyst, and with the assistance of acetic anhydride as directing group via CeH bond activation, was developed. Described method enables to form selectively CeS bond without any ligand, oxidant, and aryl/alkyl halide under mild conditions.
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پژوهشگران
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امین رستمی (نفر چهارم)، محمدعلی زلفی گل (نفر سوم)، وحید خاکی زاده (نفر دوم)، عابد رستمی (نفر اول)
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