مشخصات پژوهش

صفحه نخست /Magnetic ...
عنوان Magnetic nanoparticle-supported DABCO tribromide: a versatile nanocatalyst for the synthesis of quinazolinones and benzimidazoles and protection/deprotection of hydroxyl groups
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها magnetic Fe3O4 nanoparticles , Diazabicyclo[2.2.2]octane tribromide, 2-arylquinazolin-4(3H)-ones ,2-aryl-1H-benzo- [d]imidazoles , oxidative cyclization, 2-aminobenzamides, 1,2-phenylenediamine
چکیده 1,4-Diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles (MNPs-DABCO tribromide) as a novel heterogeneous tribromide type compound was found to be an efficient and reusable nanocatalyst for the one-pot synthesis of 2-arylquinazolin-4(3H)-ones and 2-aryl-1H-benzo- [d]imidazoles through oxidative cyclization of aldehydes with 2-aminobenzamides and 1,2-phenylenediamine, respectively. Also, MNPs-DABCO tribromide catalyzed trimethylsilylation/tetrahydropyranylation and desilylation/depyranylation of a wide variety of alcohols and phenols through changing the solvent medium at room temperature.
پژوهشگران شقایق سعادتی (نفر پنجم)، ندا درویشی (نفر چهارم)، یحیی نواسی (نفر سوم)، امید پورشیانی (نفر دوم)، امین رستمی (نفر اول)