عنوان
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A Green C-C Bond Formation Reaction between N,N-Diphenylbenzene-1,4-diamine and Michael Donors: A Convergent Paired Strategy
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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diphenylbenzene-1,4-diamine; electochemical reaction; Michael Donors; pair convergent reactions
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چکیده
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An electrochemical C-C bond formation between N,N-diphenylbenzene-1,4-diamine and CH-acid nucleophiles is described. Our data show that electrochemically generated N,N-Diphenyl-p-quinonediimine participates in Michael addition reactions with nucleophiles and via an EC mechanism converts to the products. The paired electrochemical C-C bond formation has been successfully performed in a one-pot process at a carbon electrode as the working and stainless steel as a counter electrode in an undivided cell. This method provides a green protocol over the existing methods.
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پژوهشگران
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فرزاد نیک پور (نفر سوم)، مهناز شرفی (نفر اول)، داوود نعمت الهی (نفر دوم)
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