مشخصات پژوهش

عنوان	Novel synthesis of Zirconyl Schiff base complex-functionalized MCM-48 using in oxidation of sulfides and Knoevenagel condensation reaction
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Zirconyl complex of MCM-48 , Sulfoxides ,Knoevenagel , Mesoporous
چکیده	In this study the new metal complex functionalized MCM-48 was synthesized and characterized by a number of techniques including TEM, XRD, TGA, IR, EDX, BET and ICP-AES. Zirconyl Schiff base complex of MCM-48 catalyzed the selective oxidation of a variety of sulfides to the corresponding sulfoxides in high yields. Also this modified MCM-48 could have potential application as catalyst for Knoevenagel condensation of various aldehydes with malononitrile and ethyl cyanoacetate. The catalyst could readily be separated from the reaction mixture and reused for several runs without significant loss in catalytic efficiency.
پژوهشگران	صدیقه رحیمی پناه (نفر چهارم)، صفورا روشنی (نفر سوم)، فرشید قربانی چقامارانی (نفر دوم)، مریم حجامی (نفر اول)