مشخصات پژوهش

عنوان	Copper-Catalyzed Thioetherification Reactions of Alkyl Halides, Triphenyltin Chloride, and Arylboronic Acids with Nitroarenes in the Presence of Sulfur Sources
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Copper, Alkyl Halides, Triphenyltin Chloride, Triphenyltin Chloride, Arylboronic Acids, Nitroarenes, Sulfur Sources, sulfides
چکیده	In this article, we report three odorless methods for the thioarylation and thioalkylation of different nitroarenes using alkyl halides (Br, Cl), triphenyltin chloride, and arylboronic acids as the coupling partners. Triphenyltin chloride is capable of delivering all of its phenyl groups to the product. Depending on the reaction, sodium thiosulfate pentahydrate (Na2S2O3· 5H2O), S8/KF, and S8/NaOH systems are found to be effective sources of sulfur in the presence of copper salts. The use of green solvents, inexpensive catalysts, and user-friendly starting materials has made these methods interesting from a green chemistry standpoint.
پژوهشگران	آرش قادری (نفر سوم)، امین رستمی (نفر دوم)، عابد رستمی (نفر اول)