مشخصات پژوهش

عنوان	Synthesis and characterization of transition metal dithiocarbamate derivatives of 1-aminoadamantane: Crystal Structure of (N-adamantyldithiocarbamato)Nickel(II)
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Amantadine, Dithiocarbamate, Complexation, Transition metals
چکیده	Four bis(N-adamantyldithiocarbamato)metal(II) complexes [M(S2CNHC10H15)2] (M = Ni, Zn, Cd, and Hg) were prepared by metathesis of the corresponding potassium salt, K[S2CNHC10H15]. Characterization of the prepared complexes shown that the presence of only one band in the region 1000/cm in IR spectra can be attributed to a completely symmetrical bonding of the dithiocarbamate ligand, acting in a symmetrical bidentate mode. Also the short thioureide C–N distance in X-ray analysis of Ni complex confirm the delocalization of the pi electrons over the S2CN moiety and strong double bond character.
پژوهشگران	وحید امانی (نفر چهارم)، اکرم آشوری (نفر سوم)، کتایون مرجانی (نفر دوم)، عظیم ضیایی حایمه جانی (نفر اول)