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چکیده
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Nanocomposites from nanoscale silica particles (NS), diglycidylether of bisphenol-A based epoxy (DGEBA), and 4,40-diaminobiphenyl benzidine (DAPB) as curing agent were obtained from direct blending of these materials. This homogenous mixture was cured in the oven at a particular temperature for a certain time or scanned from room temperature up to 3008C in differential scanning calorimeter (DSC). Mechanism and kinetic of the cure reaction of nanocomposite and thermal stability of the cured sample were studied with FTIR, DSC, and thermogravimetric analysis, respectively. The effect of amount of nanosilica (NS) particles as catalyst on the cure reaction of DGEBA/DAPB system was studied by the Kissinger and Ozawa equations. The existence of NS particles with hydroxyl groups in the structure catalyzes the cure reaction of DGEBA/DAPB system, increased the rate constant, and shifted the exothermic peak toward lower temperatures with increasing amount of NS particles. The activation energies of cure reaction of pure DGEBA/DAPB system obtained from two methods were in good agreement and decreased when NS particles were present in the mixture. The isothermal cure reaction at 1458C in an oven was followed by measuring the disappearance peak of epoxide group at 916 cm-1 using FTIR. The diffusive behavior of cured samples was investigated during water sorption at 258C and the experimental results fitted well according to Fick’s law. Diffusion coefficient of cured sample containing 10% NS decreased in comparison to the sample without NS particles.
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