مشخصات پژوهش

عنوان	Synthesis and characterization of organo-soluble polyamides containing triaryl imidazole pendant and ether linkage moieties: thermal, photophysical, and chemiluminescent properties
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	fluorescent; polyamides; polycondensation; solubility; thermal properties
چکیده	A new symmetrical diamine monomer containing a triaryl imidazole pendant group was successfully synthesized by the nucleophilic substitution of hydroquinone with the synthesized 2-(2-chloro-5-nitrophenyl)-4, 5-diphenyl- 1H-imidazole (I). A series of novel polyamides were prepared from the diamine monomer and various aliphatic and aromatic dicarboxylic acids via phosphorylation polyamidation. These polyamides are readily soluble in many organic solvents; their inherent viscosities ranged from 0.68 to 0.89 dl/g and gave tough and flexible films by solution-casting. They had useful levels of thermal stability associated with relatively high Tgs (186–278-C), 10% weight loss temperatures in the range of 355–482-C, and char yields at 600-C in air up to 67%. All the polyamides have fluorescence emission in dilute (0.2 g/dl) DMAc solution with maxima at 425–495nm and with the quantum yields in the range 14–28%. The chemiluminescence activity of polyamides was also studied in the presence of peroxyoxalate
پژوهشگران	سیدمجتبی امینی نسب (نفر دوم)، موسی قائمی (نفر اول)