عنوان
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Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Chiral diamino alcohols, Chiral hydroxyldiamides, Asymmetric allylic oxidation, Small chiral libraries, Chiral pool amino acids
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چکیده
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The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
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پژوهشگران
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لاله فرجی (نفر اول)، سعدی صمدی (نفر دوم)، بهروز نوتاش (نفر چهارم)، خسرو جدیدی (نفر سوم)
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