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Title
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Synthesis of new alkenyl iodobenzoate derivatives via Kharasch-Sosnovsky reaction using tert-butyl iodo benzoperoxoate and copper (I) iodide
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Type
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JournalPaper
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Keywords
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Kharasch–Sosnovsky reaction; Allylic C–H bond oxidation; tert-Butyl iodobenzoperoxoate; Alkenyl iodobenzoate; copper (I) iodide; Alkenes.
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Abstract
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The synthesis of new alkenyl iodobenzoate derivatives as allylic esters was investigated via the reaction of tert-butyl iodobenzoperoxoate with alkenes in the presence of copper salts. The best result was obtained using tert-butyl-iodobenzoperoxoate in the presence of copper (I) iodide (5 mol %) in refluxing acetonitrile with good yield (92%) in 32 hours. The structure of peresters and alkenyl iodobenzoate derivatives were characterized on the basis of their FT-IR, 1HNMR, 13CNMR, and Mass spectra.
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Researchers
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Hersh Ibrahim Rashid (Fourth Researcher), Shiva Majidian (Third Researcher), Akram Ashouri (Second Researcher), Saadi Samadi (First Researcher)
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