مشخصات پژوهش

صفحه نخست /Two intermediates in the ...
عنوان Two intermediates in the reaction between dibenzoylacetylene and enol systems in the presence of triphenylphosphine in THF/H2O
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها CH-Acids  Triphenylphosphine  Dibenzoylacetylene  Tetrasubstituted furans  Intermediates
چکیده The reaction between dibenzoylacetylene and enol systems, such as acetylaceton or cyclohexane-1,3- dione in the presence of triphenylphosphine in THF/H2O, leads to 4-acetyl-3-benzoyl-1-phenyl-1,5-hexanedione and 2-hydroxy-3-(2-oxo-2-phenylethyl)-2-phenyl-3,5,6,7- tetrahydro-1-benzofuran-4(2H)-one. Subsequently, these compounds undergo cyclization and elemination reactions in acidic dichloromethane at room temperature to produce known highly functionalized furan derivatives.
پژوهشگران بهاره آتشکار (نفر سوم)، مرتضی بیدار (نفر دوم)، فاروق نصیری (نفر اول)