مشخصات پژوهش

صفحه نخست /Selective and efficient ...
عنوان Selective and efficient oxidation of sulfides and thiols to their corresponding sulfoxides and disulfides catalyzed with praseodymium (III) and dysprosium (III) isonicotinamide (INA) complexes grafted onto modified mesoporous MCM-41
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها MCM-41 Praseodymium (III) and dysprosium (III) Isonicotinamide (INA) complexes Sulfoxides Disulfides
چکیده Praseodymium (III) and dysprosium (III) isonicotinamide (INA) complexes grafted onto modified mesoporous MCM-41 with 3-chloropropyltriethoxysilane (CPTES)), as two novel catalysts, were synthesized. The catalysts were determined using SEM, Mapping, EDX, FT-IR, TGA, XRD, ICP, and BET analysis. The catalysts (MCM-41- INA-Pr and MCM-41-INA-Dy) were further studied for the oxidation reaction of sulfur-containing compounds. Catalytic results displayed that the MCM-41-INA-Pr and MCM-41-INA-Dy show high effectiveness for promoting the oxidation reaction of sulfur-containing compounds. The catalysts could be recycled for seven runs with negligible destruction of catalytic performance.
پژوهشگران سمیه ملایی (گروه شیمی) (نفر اول)، محمد قادرمزی (نفر دوم)