عنوان
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BENZYLTRIMETHYLAMMONIUM FLUOROCHROMATE(VI): A NOVEL, EFFICIENT AND SELECTIVE OXIDANT
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Benzyltrimethylammonium fluorochromate (VI), oksidant, carbonyl compounds, alcohols.
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چکیده
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Benzyltrimethylammonium fluorochromate (VI), BTMAFC, is synthesized by reacting benzyltrimethylammonium bromide with an aqueous solution of CrO3 and HF. This new reagent, (C6H5CH2)(CH3)3N[CrO3F], is used for almost quantitative conversion of oximes into the parent ketones or aldehydes. BTMAFC is used under mild and neutral conditions for fast and selective oxidation of primary, secondary, allylic and benzylic alcohols to their corresponding carbonyl compounds, in high yields.
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پژوهشگران
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لقمان مرادی (نفر سوم)، محسن حاتمی (نفر دوم)، محمد زمان کسائی (نفر اول)
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