عنوان
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Reaction of benzoyl chlorides with Huisgen’s zwitterion: synthesis of functionalized 2,5-dihydro-1H-pyrroles and tetrasubstituted furans
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Electron-deficient acetylenes Aminofurans 2,5-Dihydro-1H-pyrrole Benzoyl chloride Isocyanides
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چکیده
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The 1:1 intermediate generated by the addition of alkyl(aryl) isocyanides to dimethyl acetylenedicarboxylate is trapped by benzoyl chloride to yield functionalized 2,5-dihydro-1H-pyrroles. The presence of electron-withdrawing groups at the para position of benzoyl chloride leads to tetrasubstituted furans. The structures of these products were confirmed by single-crystal X-ray diffraction studies.
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پژوهشگران
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انور میرزائی (نفر چهارم)، لقمان مرادی (نفر سوم)، آکو مختار پوریانی سنندج (نفر دوم)، عیسی یاوری (نفر اول)
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