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Title
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Novel and Highly Effective Method for the Trimethylsilylation of Alcohols and Phenols with Hexamethyldisilazane (HMDS), Catalyzed by I2 Generated in situ Using Fe(NO3)3 • 9 H2O/NaI under Heterogeneous and Neutral Conditions
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Type
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JournalPaper
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Keywords
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Trimethylsilylation -Alcohols-Phenols-Hexamethyldisilazane-I2 Generated in situ
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Abstract
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Structurally diverse alcohols and phenols were trimethylsilylated in a clean and efficient reaction with hexamethyldisilazane (HMDS) based on the use of I2 generated in situ from Fe(NO3)3 • 9 H2O/NaI. The reaction occurs very rapid in good-to-high yield in CH2Cl2 at room temperature, and the use of toxic and corrosive molecular I2 is avoided.
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Researchers
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Amin Rostami (Third Researcher), Sadegh Rahmati (Second Researcher), Ardeshir Khazaei (First Researcher)
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