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Title
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Photocatalytic Ring Opening of a-Epoxyketones: 1, 3-Dioxolane Formation
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Type
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JournalPaper
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Keywords
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Photocatalytic ring opening; a-epoxyketones; 1, 3-dioxolane; 2,4,6-triphenypyrylium tetrafluoroborate
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Abstract
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Photocatalytic ring opening of a-epoxyketones by 2,4,6-triphenypyrylium tetrafluoroborate (TPT) in acetone resulted in the formation of 1, 3-dioxolane as major products through C-O bond cleavage and the formation of alcoholic by-product through C-C bond cleavage. The type and nature of the substituents affect the rate of ring opening.
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Researchers
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Farzad Nikpour (Second Researcher), Hamid Reza Memarian (First Researcher)
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