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Title
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Synthesis and characterization of transition metal dithiocarbamate derivatives of 1-aminoadamantane: Crystal Structure of (N-adamantyldithiocarbamato)Nickel(II)
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Type
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JournalPaper
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Keywords
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Amantadine, Dithiocarbamate, Complexation, Transition metals
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Abstract
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Four bis(N-adamantyldithiocarbamato)metal(II) complexes [M(S2CNHC10H15)2] (M = Ni, Zn, Cd, and Hg) were prepared by metathesis of the corresponding potassium salt, K[S2CNHC10H15]. Characterization of the prepared complexes shown that the presence of only one band in the region 1000/cm in IR spectra can be attributed to a completely symmetrical bonding of the dithiocarbamate ligand, acting in a symmetrical bidentate mode. Also the short thioureide C–N distance in X-ray analysis of Ni complex confirm the delocalization of the pi electrons over the S2CN moiety and strong double bond character.
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Researchers
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Vahid Amani (Fourth Researcher), Akram Ashouri (Third Researcher), Katayoun Marjani (Second Researcher), Azim Ziyaei-Halimehjani (First Researcher)
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