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Title
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Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins
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Type
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JournalPaper
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Keywords
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Chiral diamino alcohols, Chiral hydroxyldiamides, Asymmetric allylic oxidation, Small chiral libraries, Chiral pool amino acids
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Abstract
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The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
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Researchers
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Laleh Faraji (First Researcher), Saadi Samadi (Second Researcher), Behrouz Notash (Fourth Researcher), Khosrow Jadidi (Third Researcher)
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