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Zahed Shami

Zahed Shami

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId: 36459235300
HIndex:
Faculty: Faculty of Science
Address: Department of Chemistry, School of Science, University of Kurdistan
Phone: 08733624133

Research

Title
Synthesis and characterization of a designed poly(ionic liquid-modified graphene oxide) nanocomposite: Evaluation of nitrate removal from water and antimicrobial properties
Type
JournalPaper
Keywords
antimicrobial properties, graphene oxide, ionic liquid, nanocomposite, nitrate removal, vinyl imidazolium
Year
2024
Journal Journal of Vinyl and Additive Technology
DOI
Researchers Seyed Mojtaba Amininasab ، mona naseri ، Bita Soleimani ، Marjan Hassanzadeh ، Zahed Shami

Abstract

Addressing the global challenge of water contamination, this study introduces a novel nanocomposite adsorbent—poly(ionic liquid-modified graphene oxide) (PIL-MGO)—designed to remove nitrates efficiently from water and combat microbial threats. Leveraging modified graphene oxide and vinyl imidazolium- based ionic liquid, this research synthesizes an adsorbent via a facile and cost- effective approach. The performance of PIL-MGO was rigorously analyzed through a series of characterizations, including Frontier transform infrared spectroscopy, field emitting scanning electron microscopy, energy dispersive X-ray spectroscopy, and thermogravimetric analysis, revealing its robust struc- tural composition and thermal stability. In our experimental exploration, the adsorbent showcased a remarkable nitrate removal efficiency of up to 97.53%, under optimal conditions of an initial pH of 5, room temperature, initial nitrate concentration of 30 mg/L, a contact time of 30 min, and an adsorbent dosage of 40 mg, with a significant selectivity for nitrate ions over competing anions. Moreover, regeneration of the adsorbent up to 7 cycles indicated only a marginal decline in adsorption efficiency. Furthermore, PIL-MGO demon- strated considerable antimicrobial properties against bacteria and fungi, indi- cating its dual utility in water purification and microbial inhibition. These findings suggest that the synthesized nanocomposite holds great promise for addressing environmental and health-related challenges posed by water pollut- ants. This study not only underscores the capabilities of PIL-MGO but also paves the way for further advancements in adsorbent technologies.