2025/12/5
Amin Rostami

Amin Rostami

Academic rank: Professor
ORCID:
Education: PhD.
H-Index:
Faculty: Faculty of Science
ScholarId:
E-mail: a.rostami [at] uok.ac.ir
ScopusId: View
Phone: 00988733624133
ResearchGate:

Research

Title
Synthesis, characterization and catalytic property of chiral oxo-vanadium (+)-pseudoephedrine complex supported on magnetic nanoparticles Fe3O4 in the cyanosilylation of carbonyl compounds
Type
JournalPaper
Keywords
Carbonyl compounds, TMSCN, Oxovanadium–(+)-pseudoephedrine complex, Magnetically catalyst
Year
2015
Journal CATALYSIS COMMUNICATIONS
DOI
Researchers Amin Rostami ، bahareh atashkar

Abstract

Vanadium complex of pseudoephedrine immobilized on magnetic nanoparticle Fe3O4[VO(Pseudoephedrine)@MNPs] was prepared and characterized by UV–vis, SEM, XRD, TGA, EDX, FT-IR, AGFM and elemental analysistechniques. VO(pseudoephedrine)@MNPs was found to catalyze the cyanosilylation of carbonyl compounds using TMSCN in good yields with 8–25% enantiomeric excesses under solvent-free conditions at room temperature. The catalyst was recycled up to 15 times with little loss of activity and enantioselectivity