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Title Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8
Type JournalPaper
Keywords SBA-15 · C–S coupling · S8 · Thiourea · Aryl halide · Diaryl sulfide
Abstract In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO3)2 as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N2 sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.
Researchers Raziyeh Ghafouri‑Nejad (Fourth Researcher), Farshid Ghorbani (Third Researcher), Maryam Hajjamia (Second Researcher), Zakieh Yousofvand (First Researcher)