|
Title
|
Co(II)-catalyzed regioselective clean and smooth synthesis of 2-(aryl/alkylthio) phenols via sp2 C-H bond activation
|
|
Type
|
JournalPaper
|
|
Keywords
|
Cobalt catalyst, Homogeneous catalyst, C-H bond activation, 2-(aryl/alkyl-thio) phenol
|
|
Abstract
|
The first example of a smooth, practical and useful strategy for the preparation of ortho-aryl/alkyl sulfenyl phenols by using the reaction of aryl/alkyl thiols with phenols in the presence cobalt as catalyst, and with the assistance of acetic anhydride as directing group via CeH bond activation, was developed. Described method enables to form selectively CeS bond without any ligand, oxidant, and aryl/alkyl halide under mild conditions.
|
|
Researchers
|
Amin Rostami (Fourth Researcher), MohamadAli Zolfigol (Third Researcher), Vahid Khakyzadeh (Second Researcher), Abed Rostami (First Researcher)
|