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Title Regioselective Reaction of N1-Benzyl- N2-(4-nitrophenyl)ethanediamide and Acetylenic Esters
Type JournalPaper
Keywords Intramolecular Wittig reaction; Acetylenic esters; Triphenylphosphine; 2-Oxo-5-pyrrolidines; 5-Oxo-2,5-dihydro-1H-pyrroles
Abstract The regioselective reaction of N1-benzyl-N2-(4-nitrophenyl)ethanediamide with dialkyl acetylenedicarboxylates or alkyl propiolates in the presence of triphenylphosphine leads to dialkyl 4-benzylamino-1-(4-nitrophenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2,3-dicarboxylates or alkyl 4-benzylamino- 1-(4-nitrophenyl)-2-oxo-5-pyrrolidinecarboxylates in good yields
Researchers Hoorieh Djahaniani (Fourth Researcher), Farough Nasiri (Third Researcher), Loghman Moradi (Second Researcher), yavari Issa (First Researcher)