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Saadi Samadi

Saadi Samadi

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId: 36017420200
Faculty: Faculty of Science
Address: Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Code 66177-15175, Sanandaj, Iran.
Phone: 4264

Research

Title
Mukaiyama-Michael addition of propiophenone enole silane to N-cinamoyle oxazolidinone and diethyl 2-benzylidene malonate
Type
Presentation
Keywords
Mukaiyama-Michael addition ,enone,diethyl benziliden,BF3.OEt2
Year
2013
Researchers Saber Nazari ، Saadi Samadi ، Khosrow Jadidi

Abstract

In 1974-1976, Mukaiyama and co-workers introduced a version of the Michael addition reaction wherein an enolsilane reacts with an enone under conditions of Lewis acid atalysis [1]. The conjugate addition of enolsilanes to α,β-unsaturated carbonyl derivatives, the Mukaiyama-Michael reaction has been shown to be a mild, versatile method for carboncarbon bond formation [2]. This process would provide access to valuable 1,5-dicarbonyl synthons which are important building blocks in organic synthesis. In our work addition of propiophenone enol silane to diethyl benziliden malonate and cinamoyl oxazolidinone using BF3.OEt2 as lewis acid gave product in good yield