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Saadi Samadi

Saadi Samadi

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId: 36017420200
Faculty: Faculty of Science
Address: Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Code 66177-15175, Sanandaj, Iran.
Phone: 4264

Research

Title
Copper-catalyzed synthesis of diarylamines using p-toluene sulfonamides and benzhydrol derivatives under homogeneous borrowing hydrogen conditions
Type
JournalPaper
Keywords
Diaryl amine, Benzhydrol, sulfonamides, Copper salt, Bisphosphine ligands, Borrowing Hydrogen (BH) mechanism.
Year
2020
Journal COMPTES RENDUS CHIMIE
DOI
Researchers Akram Ashouri ، Saadi Samadi ، Masoud Ahmadian ، Behzad Nasiri

Abstract

Diarylamines were synthesized using p-toluene sulfonamides with benzhydrol derivatives in the presence of a copper/bisphosphine complex by Borrowing Hydrogen (BH) mechanism, yielding <98% under clean and mild reaction conditions. The use of readily available and cost-effective copper salts, short reaction times, high yield and reaction rates are highlighted