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Mohammad Ghadermazi

Mohammad Ghadermazi

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 17345456400
Faculty: Faculty of Science
Address:
Phone: 0871-6624133

Research

Title
Immobilization of Pd(0) complex on the surface of SBA-15: A reusable catalyst for the synthesis of 5-substituted tetrazoles, sulfides and sulfoxides
Type
JournalPaper
Keywords
SBA-15 Palladium Sulfide Sulfoxide 5-Substituted tetrazol
Year
2019
Journal POLYHEDRON
DOI
Researchers Tayebe Tamoradi ، Arash Ghorbani-Choghamarani ، Mohammad Ghadermazi

Abstract

A simple and efficient method for the synthesis of 5-substituted tetrazoles, sulfides and sulfoxides in the presence of Pd(0) complex immobilized on mesoporous SBA-15 as an efficient, recoverable and thermally stable mesostructure has been reported. Also, the prepared mesostructure was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray mapping, energy-dispersive X-ray spectroscopy, N2 adsorption and desorption, inductively coupled plasma optical emission spectroscopy and thermal gravimetric analysis. Then, this mesostructured catalyst was applied in the synthesis of 5- substituted tetrazoles, sulfides and sulfoxides. The approach described here offers advantages such as short reaction times, high yield, purity yields, simple and eco- friendly, easy work-up. More importantly, this nanohybrid robust catalyst did not undergo metal leaching and applied several times without any decrease in catalytic activity