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Mohammad Ghadermazi

Mohammad Ghadermazi

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 17345456400
Faculty: Faculty of Science
Address:
Phone: 0871-6624133

Research

Title
Selective and efficient oxidation of sulfides and thiols to their corresponding sulfoxides and disulfides catalyzed with praseodymium (III) and dysprosium (III) isonicotinamide (INA) complexes grafted onto modified mesoporous MCM-41
Type
JournalPaper
Keywords
MCM-41 Praseodymium (III) and dysprosium (III) Isonicotinamide (INA) complexes Sulfoxides Disulfides
Year
2020
Journal SOLID STATE SCIENCES
DOI
Researchers Somayeh Molaei ، Mohammad Ghadermazi

Abstract

Praseodymium (III) and dysprosium (III) isonicotinamide (INA) complexes grafted onto modified mesoporous MCM-41 with 3-chloropropyltriethoxysilane (CPTES)), as two novel catalysts, were synthesized. The catalysts were determined using SEM, Mapping, EDX, FT-IR, TGA, XRD, ICP, and BET analysis. The catalysts (MCM-41- INA-Pr and MCM-41-INA-Dy) were further studied for the oxidation reaction of sulfur-containing compounds. Catalytic results displayed that the MCM-41-INA-Pr and MCM-41-INA-Dy show high effectiveness for promoting the oxidation reaction of sulfur-containing compounds. The catalysts could be recycled for seven runs with negligible destruction of catalytic performance.