1403/02/07
محمد قادرمزی

محمد قادرمزی

مرتبه علمی: استاد
ارکید:
تحصیلات: دکترای تخصصی
اسکاپوس: 17345456400
دانشکده: دانشکده علوم پایه
نشانی:
تلفن: 0871-6624133

مشخصات پژوهش

عنوان
Metal Organic Structure Built from Binuclear Sn(IV) Complex: Synthesis, Characterization, and X-Ray Structural Studies
نوع پژوهش
JournalPaper
کلیدواژه‌ها
metal organic structure, Sn(IV) atom, proton transfer, binuclear neutral complex, crystal structure, hydrogen bond, π-interaction
سال
2016
مجله Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
شناسه DOI
پژوهشگران Shabnam Sheshmani ، Mohammad Ghadermazi

چکیده

3D metal organic structure of a p-block metal ion, Sn(IV) atom, formulated as [Sn(pydc)(HOC2H5)(CH3)2]2, was synthesized and characterized. This complex is binuclear with two bridging oxygen atoms of carboxylate groups. Each of the two Sn(IV) atoms is also coordinated by the chelate (pydc)2– ligand and two terminal CH3 groups as well as by one terminal HOC2H5 group. Based upon the molecular structure analysis, the coordination environment around each Sn(IV) atom is distorted pentagonal bipyramid. The hydrogen bonding between carbonyl and ethoxy groups of two neighboring neutral complexes produce the Zig-Zag arrangements