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Farshid Ghorbani

Farshid Ghorbani

Academic rank: Associate Professor
ORCID:
Education: PhD.
ScopusId: 23027283400
Faculty: Faculty of Natural Resources
Address: Department of Environmen, Faculty of Natural Resource, University of Kurdistan, P.O. Box: 416, 66177-15175 Sanandaj, Iran
Phone: 087-6620551

Research

Title
Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8
Type
JournalPaper
Keywords
SBA-15 · C–S coupling · S8 · Thiourea · Aryl halide · Diaryl sulfide
Year
2018
Journal JOURNAL OF POROUS MATERIALS
DOI
Researchers Zakieh Yousofvand ، Maryam Hajjamia ، Farshid Ghorbani ، Raziyeh Ghafouri‑Nejad

Abstract

In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO3)2 as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N2 sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.