Iron-modified titanium dioxide nanostructured catalyst was synthesized by sol-gel method. Due to the important impacts of surface properties on the catalytic activity, the catalyst surface is investigated. To have a complete characterization of the catalyst, TEM, SEM, XPS, XRD, BET, and TGA-DTA thechniques were used. XRF analysis reveals the iron loading of the synthesized catalyst as Fe2O3/TiO2=0.21%. XRD results imply that the catalyst is composed of anatase and rutile phase. The SEM image indicates the mesoporosity of the nanoparticles. Clusters are observable in the TEM images. The main objective of activity tests is focused upon the comparative evaluation of H2O2 addition and the application of air bubbling. Experimental results specified that the optimum amount for H2O2 dosage is 12.5 ml. Moreover, it has been observed that an increase in the aeration flow rate shows a positive effect on the degradation of phenol and the optimum aeration flow is 9 l/min. Furthermore, it has been shown that the addition of copper as additive ion to phenol solution boosts the degradation efficiency after 120 min (43.75%) was attained under this condition.
