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Amin Rostami

Amin Rostami

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 7005439034
Faculty: Faculty of Science
Address: Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Code 66177-15175, Sanandaj, Iran
Phone: 00988733624133

Research

Title
Synthesis, characterization and catalytic property of chiral oxo-vanadium (+)-pseudoephedrine complex supported on magnetic nanoparticles Fe3O4 in the cyanosilylation of carbonyl compounds
Type
JournalPaper
Keywords
Carbonyl compounds, TMSCN, Oxovanadium–(+)-pseudoephedrine complex, Magnetically catalyst
Year
2015
Journal CATALYSIS COMMUNICATIONS
DOI
Researchers Amin Rostami ، bahareh atashkar

Abstract

Vanadium complex of pseudoephedrine immobilized on magnetic nanoparticle Fe3O4[VO(Pseudoephedrine)@MNPs] was prepared and characterized by UV–vis, SEM, XRD, TGA, EDX, FT-IR, AGFM and elemental analysistechniques. VO(pseudoephedrine)@MNPs was found to catalyze the cyanosilylation of carbonyl compounds using TMSCN in good yields with 8–25% enantiomeric excesses under solvent-free conditions at room temperature. The catalyst was recycled up to 15 times with little loss of activity and enantioselectivity