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Amin Rostami

Amin Rostami

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 7005439034
Faculty: Faculty of Science
Address: Department of Chemistry, Faculty of Science, University of Kurdistan, Zip Code 66177-15175, Sanandaj, Iran
Phone: 00988733624133

Research

Title
Magnetic nanoparticle immobilized N-propylsulfamic acid: The chemoselective, efficient, green and reusable nanocatalyst for oxidation of sulfides to sulfoxides using H2O2under solvent-free conditions
Type
JournalPaper
Keywords
Magnetic nanoparticle, Nanocatalyst, N-Propylsulfamic acid H2O2, Sulfide, Sulfoxide
Year
2013
Journal JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
DOI
Researchers Amin Rostami ، Bahman Tahmasbi ، Fatemeh Abedi ، Zahra Shokri

Abstract

An efficient and eco-friendly method is reported for the chemoselective oxidation of sulfides to sulfox-ides in good to high yields using 30% H2O2in the presence of catalytic amounts of N-Propylsulfamic acid supported onto magnetic Fe3O4nanoparticles (MNPs-PSA) under solvent-free conditions at room tem-perature. Various types of aromatic and aliphatic sulfides possessing functional groups such as alcohol, ester, and aldehyde are successfully and selectively oxidized without affecting sensitive functionalities. The magnetic nanocatalyst can be readily recovered easily by applying an external magnet device and reused for at least 10 reaction runs without considerable loss of reactivity