Synthesis and characterization of transition metal dithiocarbamate derivatives of ۱-aminoadamantane: Crystal Structure of (N-adamantyldithiocarbamato)Nickel(II)

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عنوان	Synthesis and characterization of transition metal dithiocarbamate derivatives of 1-aminoadamantane: Crystal Structure of (N-adamantyldithiocarbamato)Nickel(II)
نوع پژوهش	JournalPaper
کلیدواژه‌ها	Amantadine, Dithiocarbamate, Complexation, Transition metals
سال	2011
مجله	INORGANICA CHIMICA ACTA
شناسه DOI
پژوهشگران	Azim Ziyaei-Halimehjani ، Katayoun Marjani ، Akram Ashouri ، Vahid Amani

چکیده

Four bis(N-adamantyldithiocarbamato)metal(II) complexes [M(S2CNHC10H15)2] (M = Ni, Zn, Cd, and Hg) were prepared by metathesis of the corresponding potassium salt, K[S2CNHC10H15]. Characterization of the prepared complexes shown that the presence of only one band in the region 1000/cm in IR spectra can be attributed to a completely symmetrical bonding of the dithiocarbamate ligand, acting in a symmetrical bidentate mode. Also the short thioureide C–N distance in X-ray analysis of Ni complex confirm the delocalization of the pi electrons over the S2CN moiety and strong double bond character.

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چکیده